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HomeMy WebLinkAboutHand Sanitizer SDS v5Page 1 of 6 SAFETY DATA SHEET Hand Sanitizer Date Issued: 05/05/2020 SDS No: 001114 Date-Revised: 4/21/2020 Revision No: 3 PRODUCT NAME: Hand Sanitizer MANUFACTURER: Heritage Distilling Company 4021 Harborview Dr. Gig Harbor, WA. 98332 Service Number: 1-253-509-0008 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC (US Transportation) :(800) 424 - 9300 CANUTEC (Canadian Transportation) :(613) 996 – 66 GHS CLASSIFICATIONS Health: Flammable Liquids, Category 3 GHS LABEL Flamable HAZARD STATEMENTS H225: Flammable liquid and vapors PRECAUTIONARY STATEMENT(S) Prevention: P210: Keep away from heat, hot surface, sparks, open -No smoking. P233 Keep container tightly closed. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. Prevention: P210 Keep away from heat, hot surfaces, sparks, open sources. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment P241 Use explosion-proof electrical/ ventilating/ light P242 Use only non-sparking tools. P243 Take precautionary measures against static disch P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ sp P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection. 2.HAZARDS IDENTIFICATION 1. PRODUCT AND COMPANY IDENTIFICATION Page 2 of 6 Hand Sanitizer Response: P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Potential Health Effects Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential Chemical Name Vol. % CAS Ethanol 80.00 64-17-5 Distilled Water 14.38 7732-18-5 Hydrogen Peroxide (3% Solution) 4.17 772-84-1 Glycerin 1.45 56-81-5 EYES: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medical attention, if irritation occurs or persists. 3. COMPOSITION / INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES Page 3 of 6 Hand Sanitizer SKIN: Wash with soap and water for at least 15 minutes. Get medical attention, if irritation develops or persists. INGESTION: DO NOT INDUCE VOMITING. Do not attempt to give anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head below hips to prevent aspiration of liquid into the lungs. Get medical attention. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, oxygen should be administered by qualified personnel. Seek immediate medical attention. SIGNS AND SYMPTOMS OF OVEREXPOSURE ACUTE TOXICITY: Shortness of breathing, confused behavior, redness of skin, swelling of tissues, watery eyes, and nausea. FLAMMABLE CLASS: Class 2 flammable liquid. EXTINGUISHING MEDIA: Use "alcohol resistant" foam, dry chemical, or CO2. Water may be ineffective, but water applied as a spray can absorb some of the fire's heat and should be used to keep fire-exposed containers cool. HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and unidentified organic compounds may be formed during combustion. EXPLOSION HAZARDS: When heated above the flash point, this material emits flammable vapors which, when mixed with air, can burn or be explosive. Fine mists or sprays may be flammable at temperatures below the flash point. FIRE FIGHTING PROCEDURES: WARNING! Flammable Liquid. Clear fire area of unprotected personnel. Do not enter confined fire space without full bunker gear, including a positive pressure NIOSH approved SCBA. Cool fire exposed containers with water. GENERAL PROCEDURES: WARNING. Flammable. Ventilate area of leak or spill. Remove all sources of 5. FIRE FIGHTING MEASURES 6. ACCIDENTAL RELEASE MEASURES Page 4 of 6 Hand Sanitizer ignition. Clean-up personnel require protective clothing and respiratory protection from vapors. Only specially trained or qualified personnel should handle the emergency. GENERAL PROCEDURES: Keep away from heat, sparks, and flame. Surfaces that are hot may ignite even liquid product in the absence of sparks or flame. Extinguish pilot lights, cigarettes and turn off other sources of ignition prior to use and until all vapors are gone. COMMENTS: KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition; they may explode and cause injury or death. EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS OSHA PEL ACGIH TLV SupplierOEL Chemical Name ppm mg/m3 ppm mg/m 3 ppm mg/m3 Ethanol TWA 1000 1900 1000 1884 400 980 STEL 400 1,225 Hydrogen Peroxide TWA 1 1 1 1 STEL 1 1 1 1 ENGINEERING CONTROLS: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Exhaust air may need to be cleaned by scrubbers or filters to reduce environmental contamination. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Use chemical safety goggles and/or full face shield where splashing is possible. Contact lenses should not be worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work areas. SKIN: Wear resistant gloves (consult your safety equipment supplier). To prevent repeated or prolonged skin contact, wear impervious clothing and boots. RESPIRATORY: If exposure may or does exceed occupational exposure limits (Sec. 8) use a NIOSH approved respirator to prevent overexposure. In accord with 29 CFR 1910.134 use either an atmosphere-supplying respirator or an air-purifying respirator for organic vapors. PROTECTIVE CLOTHING: Where splashing is possible, full chemically resistant protective clothing (e.g., acid suit) and boots are required. WORK HYGIENIC PRACTICES: Use good personal hygiene when handling this product. Wash hands after use, before eating, drinking, smoking, or using the toilet. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. w 7. HANDLING AND STORAGE 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 5 of 6 Hand Sanitizer PHYSICAL STATE: Liquid ODOR: Alcohol odor. APPEARANCE: Clear COLOR: Water-white. pH: NA = Not Applicable PERCENT VOLATILE: no data available FLASHPOINT AND METHOD: no data available FLAMMABLE LIMITS: no data available AUTOIGNITION TEMPERATURE: no data available VAPOR PRESSURE: no data available VAPOR DENSITY: Heavier than air. BOILING POINT: (173°F) to (212°F) FREEZING POINT: NDA = no data available. MELTING POINT: (-173°F) SOLUBILITY IN WATER: Soluble EVAPORATION RATE: Slower than ether. DENSITY: 6.69 SPECIFIC GRAVITY: 0.79 to 0.81 15.5°C/60°F (VOC): 6.180 LBS./gal. STABLE: Yes POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid heat, sparks, flame and contact with strong oxidizing agents. Do not store or handle in aluminum equipment at temperatures above 120 deg. F. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide and unidentified organic compounds may be formed during combustion. There should be no decomposition if stored and applied as directed. INCOMPATIBLE MATERIALS: This product is incompatible with strong acids or bases, oxidizers, alkali metals, and halogens. TARGET ORGANS: This product contains ethanol. Alcoholic beverage consumption has been associated with brain damage, heart damage, and pancreatitis in humans. The relevance of these findings to ethanol exposure in industrial environments is uncertain. ECOTOXICOLOGICAL INFORMATION: Avoid uncontrolled releases of this material. Where spills are 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION Page 6 of 6 Hand Sanitizer possible, a comprehensive spill response plan should be developed and implemented. DISPOSAL METHOD: The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. EMPTY CONTAINER: KEEP OUT OF REACH OF CHILDREN! Empty containers retain product residue and can be dangerous. Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse. Do not pressurize, cut weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks static electricity, or other sources of ignition. RCRA/EPA WASTE INFORMATION: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Hand Sanitizer PRIMARY HAZARD CLASS/DIVISION: 2 UN/NA NUMBER: UN 1170 PACKING GROUP: II NAERG: 127 LABEL: Flammable liquid UNITED STATES DOT LABEL SYMBOL AND HAZARD CLASSIFICATION Flammable Liquid S28: After contact with skin, wash immediately with plenty of water and soap. R68/22: Harmful: possible risk of irreversible effects if swallowed. SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: Yes PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes 313 REPORTABLE INGREDIENTS: To the best of our knowledge, this product is not listed as a toxic chemical under Section 313 of SARA Title III. 13. DISPOSAL CONSIDERATIONS 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION Page 7 of 6 Hand Sanitizer 302/304 EMERGENCY PLANNING EMERGENCY PLAN: To the best of our knowledge, this product is not listed as an extremely hazardous substance. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: Listed. CANADA WHMIS HAZARD SYMBOL AND CLASSIFICATION Flammable Liquid R20: Harmful by inhalation. R40/21/22: Harmful : possible risk of irreversible effects in contact with skin and if swallowed GENERAL COMMENTS: The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. REASON FOR ISSUE: New product. PREPARED BY: COMPLIANCE REVISION SUMMARY: This SDS replaces the 9/10/2013 MSDS. HMIS RATING NFPA CODES MANUFACTURER DISCLAIMER: The information contained herein is based on the data available to us and is believed to be accurate. However, Heritage Distilling Company, Inc. makes no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. Heritage Distilling Company Inc. assumes no responsibility for injuries from the use of the product described herein. HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 PERSONAL PROTECTION H 16. OTHER INFORMATION