HomeMy WebLinkAboutHillyard Arsenal 1 QT Plus SDS HIL00824 Feb 2020SAFETY DATA SHEET
1. Identification
Product identifier Q.T. Plus
Other means of identification
SDS number 538N02A
Product code HIL00824
6836-77-1658Product registration
number
Recommended use Disinfectant/Cleaner
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name HILLYARD INDUSTRIES
Address 302 North Fourth St.
St. Joseph, MO 64501
Contact person Regulatory Affairs
Telephone number (816) 233-1321 (Ext. 8285)
Fax (816) 383-8485
E-mail regulatoryaffairs@hillyard.com
Emergency telephone #(800) 424-9300
(Only in the event of chemical emergency involving a spill, leak, fire, exposure or
accident involving chemicals)
2. Hazard(s) identification
Not classified.Physical hazards
Category 1Skin corrosion/irritationHealth hazards
Category 1Serious eye damage/eye irritation
Category 1Sensitization, respiratory
Category 1Sensitization, skin
Category 2Reproductive toxicity
Category 3Hazardous to the aquatic environment, acute
hazard
Environmental hazards
Category 3Hazardous to the aquatic environment,
long-term hazard
Not classified.OSHA defined hazards
Label elements
Signal word Danger
Hazard statement Causes severe skin burns and eye damage. Causes serious eye damage.
Precautionary statement
Prevention Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective
clothing/eye protection/face protection.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. Wash contaminated clothing before reuse.
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Material name: Q.T. Plus
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Storage Store locked up.
Disposal Buyer assumes all risk and liability associated with disposal of this product (original concentration
or dilution) in violation of applicable law in compliance with applicable federal, state and local
requirements.
Hazard(s) not otherwise
classified (HNOC)
Harmful to aquatic life. Harmful to aquatic life with long lasting effects.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
68424-85-1Alkyl dimethyl benzyl ammonium
chloride (C12-16)
5 - < 10
68424-95-3N,N-Dialkyl(C8-10)-N,N-dimethylam
monium Chloride
5 - < 10
68439-46-3Alcohols, C9-11, ethoxylated 3 - < 5
64-17-5Ethanol 1 - < 3
64-02-8Tetrasodium ethylenediamine
tetraacetate
1 - < 3
Other components below reportable levels 70 - < 80
FRESH LEMON FRAGRANCE
17-866
0.3
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician
or poison control center immediately.
Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Chemical burns
must be treated by a physician. Call a physician or poison control center immediately. For minor
skin contact, avoid spreading material on unaffected skin.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important
symptoms/effects, acute and
delayed
Corrosive effects. May cause temporary blindness and severe eye damage. Symptoms may
include stinging, tearing, redness, swelling, and blurred vision.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. In case of shortness of breath,
give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods Move container from fire area if it can be done without risk.
General fire hazards No unusual fire or explosion hazards noted.
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6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate personal protective equipment. Do not breathe mist or vapor. Do not
touch damaged containers or spilled material unless wearing appropriate protective clothing.
Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for
containment and cleaning up
Extinguish all flames in the vicinity. This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Prevent entry into waterways, sewer, basements or confined areas. Following product recovery,
flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills in original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic
environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid
discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Do not breathe mist or vapor. Do not get this material in contact with eyes. Do not get this material
in contact with skin. Avoid prolonged exposure. Do not get this material on clothing. Provide
adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices. Wash hands thoroughly after handling. Avoid release to the environment. Do
not empty into drains.
Conditions for safe storage,
including any incompatibilities
Do not contaminate water, food or feed by storage or disposal. Pesticide Storage: Open dumping
is prohibited. Store in original container in areas inaccessible to children. Store locked up. Store in
original tightly closed container. Store in a cool, dry place out of direct sunlight. Store away from
incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 1900 mg/m3Ethanol (CAS 64-17-5)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
STEL 1000 ppmEthanol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 1900 mg/m3Ethanol (CAS 64-17-5)
1000 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear eye/face protection. Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection Wear protective gloves.
Other Wear appropriate chemical resistant clothing. It may provide little or no thermal protection.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
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Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using, do not eat, drink or smoke. Do not get this material on clothing. Always observe good
personal hygiene measures, such as washing after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove
contaminants.
9. Physical and chemical properties
Appearance Clear, yellow liquid
Physical state Liquid.
Form Liquid.
Color Yellow
Odor Lemon odor
Odor threshold Not available
pH 12 - 13 concentrate
Melting point/freezing point Not applicable / Not available
Initial boiling point and boiling
range
209 °F (98.33 °C)
Flash point > 200.0 °F (> 93.3 °C) Tag Closed Cup
Evaporation rate < 1 (ethyl ether = 1)
Flammability (solid, gas)Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 17.8 mm Hg
Vapor density 0.6 Air =1
Relative density 1.0172 at 77°F
Solubility(ies)
Solubility (water)Not available.
Partition coefficient
(n-octanol/water)
Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Other information
Density 8.47 lb/gal
Percent volatile 78.5 - 80.5 %
VOC (Weight %)1.36 %
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid Avoid temperatures exceeding the flash point. Reacts violently with strong acids. This product may
react with oxidizing agents. Do not mix with other chemicals. Contact with incompatible materials.
Incompatible materials Oxidizing agents. Acids.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation May cause irritation to the respiratory system.
Skin contact Causes severe skin burns.
Eye contact Causes severe eye burns. Causes serious eye damage.
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Ingestion Causes digestive tract burns.
Symptoms related to the
physical, chemical and
toxicological characteristics
Burning pain and severe corrosive skin damage. Symptoms may include stinging, tearing,
redness, swelling, and blurred vision. Permanent eye damage including blindness could result.
Information on toxicological effects
Acute toxicity
Test ResultsProduct Species
Q.T. Plus
LC50 Mouse
Inhalation
Acute
3669.7249 mg/l, 2 Hours estimated
3055.4407 mg/l, 4 Hours estimated
Rat 7522.9355 mg/l, 0.5 Hours estimated
7400 mg/l, 2 Hours estimated
4403.6699 mg/l, 4 Hours estimated
LD50 Guinea pig
Oral
2243.5898 g/kg estimated
Monkey 24096.3848 g/kg estimated
Rat 2267.3569 g/kg estimated
Test ResultsComponents Species
Ethanol (CAS 64-17-5)
LC50 Mouse
Inhalation
Acute
39 mg/l, 4 Hours
Rat 20000 ppm, 10 Hours
LD50 Guinea pig
Oral
5.6 g/kg
Mouse 3450 mg/kg
Rat 6.2 g/kg
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye
irritation
Causes severe eye burns. Causes serious eye damage.
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Possible reproductive hazard.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard. Prolonged inhalation may be harmful.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.
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Product Test ResultsSpecies
Q.T. Plus
Aquatic
EC50Crustacea 121.9153 mg/l, 48 hours estimatedDaphnia
LC50Fish 145.5562 mg/l, 96 hours estimatedFish
Components Test ResultsSpecies
Alcohols, C9-11, ethoxylated (CAS 68439-46-3)
Aquatic
EC50Crustacea 2.9 - 8.5 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 6 - 12 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Alkyl dimethyl benzyl ammonium chloride (C12-16) (CAS 68424-85-1)
Aquatic
LC50Fish 10.4 - 19.1 mg/l, 96 hoursStriped bass (Morone saxatilis)
Ethanol (CAS 64-17-5)
Aquatic
EC50Crustacea 7.7 - 11.2 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
Ethanol -0.31
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal of excess
pesticide, spray mixture or rinsate is a violation of Federal Law. If these wastes cannot be
disposed of by use according to label instructions, contact your State Pesticide or Environmental
Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for
guidance.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Container Disposal: Nonrefillable container. Do not reuse or refill this container. Wrap empty
container and put in trash.
14. Transport information
DOT
UN1903UN number
Disinfectants, Corrosive Liquid, n.o.s. (N,N-Dialkyl(C8-10)-N,N-dimethylammonium Chloride,
N-Alkyl(C12-16)-N,N-dimethyl-N-benzylammonium)
UN proper shipping name
8Class
Transport hazard class(es)
-Subsidiary risk
8Label(s)
IIIPacking group
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
153ERG number
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DOT
General information PACKAGES 1 GALLON AND SMALLER ARE SHIPPED LIMITED QUANTITY OR ORM-D
This material is regulated under IATA and IMDG regulations. Contact manufacturer for shipping
instructions.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Safe Drinking Water Act
(SDWA)
Not regulated.
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FIFRA Information FIFRA: This product is a U.S. EPA Registered pesticide, EPA Reg. No. 6836-77-1658, and is
subject to certain labeling requirements under Federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets (SDS), and
for workplace labels of non-pesticide products. The hazard information required on the pesticide
label is reproduced here.
PRECAUTIONARY STATEMENTS – HAZARDS TO HUMANS AND DOMESTIC ANIMALS.
DANGER
Corrosive. Causes irreversible eye damage and skin burns. Do not get in eyes, on skin, or on
clothing. Wear protective eyewear (goggles, face shield, or safety glasses), protective clothing and
protective (rubber or chemical resistant) gloves. Harmful if swallowed or if absorbed through the
skin. Wash thoroughly with soap and water after handling and before eating, drinking, chewing
gum, using tobacco or using the toilet. Remove contaminated clothing and wash clothing before
reuse.
FIRST AID: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes.
Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye. IF ON SKIN OR
CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. IF SWALLOWED: Call a poison control center or doctor immediately for treatment
advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to
do so by a poison control center or doctor. Do not give anything by mouth to an unconscious
person.
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.
Call a poison control center or doctor for treatment advice. Have the product container or label with
you when calling a poison control center or doctor or going for treatment.
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Ethanol (CAS 64-17-5)
US. New Jersey Worker and Community Right-to-Know Act
Ethanol (CAS 64-17-5)
US. Pennsylvania Worker and Community Right-to-Know Law
Ethanol (CAS 64-17-5)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 05-26-2015
Revision date 02-04-2016
Version #02
HMIS® ratings Health: 3*
Flammability: 0
Physical hazard: 0
Disclaimer No representations or warranties, either express or implied, of merchantability, fitness for a
particular purpose, or of any nature are made with respect to the product(s) or information
contained in this material safety data sheet. The information and recommendations contained in
this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational
Safety and Health Standards Hazard Communication Rule. All information contained herein is
presented in good faith and is believed to be appropriate and accurate. The buyer or user
assumes all risks associated with the use, misuse or disposal of this product. The buyer or user is
responsible to comply with all federal, state or local regulations concerning the use, misuse or
disposal of these products.
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Revision Information Product and Company Identification: Alternate Trade Names
Physical & Chemical Properties: Multiple Properties
Toxicological Information: Toxicological Data
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Material name: Q.T. Plus
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