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SDS Husky 814 Quat tb 2016QUAT TUBERCULOCIDAL HUSKY 814 Q/T TUBERCULOCIDAL SPRAY DISINFECTANT Version: 002 Date issued: 31. 12. 2014 Revision Date: 14. 04. 2016 Page 1 of 3 CANBERRA CORPORATION SAFETY DATA SHEET 1. Identification Product Identifier: QUAT TUBERCULOCIDAL HUSKY 814 Q/T TUBERCULOCIDAL SPRAY DISINFECTANT Application or recommended use: Hard surface spray disinfectant cleaner Restrictions on use: Do not use in any fashion not specified on the product label. Manufacturer / supplier: Canberra Corporation 3610 N. Holland-Sylvania Rd. Toledo, Ohio 43615 USA Telephone: 419-841-6616 Emergency phone: 800-832-8992 National Poison Center: 800-222-1222 2. Hazards Identification GHS Classification: Classification of this mixture in accordance with paragraph (d) of §1910.1200. Eye Damage/Irritation - Category 2A Label Elements: Symbol: Signal word: WARNING Hazard statements: Causes serious eye irritation. Precautionary statements: Wash hands, face and any skin contact thoroughly after handling. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Other Hazards: None known 3. Composition / Information on Ingredients Chemical characterization: Mixture of water, detergents, germicides and auxiliary agents. Hazardous ingredients: The exact percentage of composition has been withheld as a trade secret. 8% *2-(2-Butoxyethoxy)ethanol CAS 112-34-5, EINECS/ELINCS 203-961-6 1.6% Tetrasodium EDTA CAS 64-02-8, EINECS/ELINCS 200-573-9 Other ingredients (> 1%): > 88% Water CAS 7732-18-5, EINECS/ELINCS 231-791-2 4. First-Aid Measures Symptoms: Burning or irritation of affected areas. May cause minor skin irritation. Causes serious eye irritation. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: Move person to fresh air. If respiratory irritation or dizziness occurs, seek immediate medical assistan ce. Skin Contact: Remove contaminated clothing and wash before reuse. Wash contaminated area with soap and water for 15 -20 minutes. If skin irritation occurs, get medical advice/attention. Eye Contact: Hold eye open and rinse slowly and gently with water for 15 -20 minutes. Remove contact lenses, if present, after first 5 minutes, then continue rinsing eye. If eye irritation persists, get medical advice/attention. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to a person who is unconscious or convulsing. If vomiting occurs, keep head below hips to reduce risk of aspiration. Note to Physician: Treat exposed patients symptomatically. 5. Fire-Fighting Measures Suitable Extinguishing Media: Not applicable. Product is not a fire hazard. Unsuitable Extinguishing Media: High pressure water jet. Specific hazards in case of fire: None known. Special Fire Fighting Precautions: Fire fighters should wear appropriate protective equipment, including self -contained breathing apparatus and impervious clothin g. 6. Accidental Release Measures Emergency Procedures: Depending on the extent of release, consider the need for restriction of access to spill area. Personal Precautions: Do not eat, drink or smoke during clean up. Wear protective clothing, eye protection and impervious gloves (e.g. neoprene). Wash thoroughly after clean up. Environmental Precautions: Prevent spills from entering storm sewers/drains or contact with soil. QUAT TUBERCULOCIDAL HUSKY 814 Q/T TUBERCULOCIDAL SPRAY DISINFECTANT Version: 002 Date issued: 31. 12. 2014 Revision Date: 14. 04. 2016 Page 2 of 3 6. Accidental Release Measures (cont.) Clean up Methods: Small spills may be wiped up and rinsed with water. For larger spills, contain spill with inert material (sand, clay). Transfer material to labeled containers for recovery or proper disposal. Afte r removal, flush area with water. Follow good industrial hygiene practices. 7. Handling and Storage Precautions for Safe Handling: Read label before use. Avoid contact with skin or eyes. Wash hands, face and any skin contact thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves, eye protection, face protection. Use product only according to label directions. If unsure about safe use, con tact your supervisor. Conditions for Safe Storage: Keep out of reach of children. Do not contaminate water, food or feed by storage and disposal. Store in tightly closed, original container in a cool (10˚ - 30˚C), dry area. Incompatibility: Anionic detergents inactivate material. 8. Exposure Controls / Personal Protection Components with occupational exposure limits: None Engineering Controls: Proper ventilation in accordance with good industrial hygiene should be provided. Personal Protective Equipment Respiratory: Respiratory protection is not necessary under normal conditions of use Gloves: Water impervious gloves (latex or neoprene rubber) recommended for continuous use. Eye Protection: Chemical resistant goggles or face protection. Other: Protective clothing (long sleeves, pants), eyewash, safety shower are always advisable when working with chemicals. 9. Physical and Chemical Properties Physical State - Liquid Auto-ignition temperature - Not applicable Color - None Flash Point - None Odor - Lemon Flammability - Not applicable Odor Threshold - No data available Flammability Limits - Not applicable Boiling Point - 212°F Partition coefficient - Not applicable Decomposition temperature - No data available Solubility (Water) - Complete Freezing Point - 32°F Vapor Density - No data available pH (Neat) - 11.8 - 12.8 Vapor Pressure - No data available Relative Density - 1.015 Viscosity - Water thin Evaporation Rate - Similar to water % VOC - < 1 (Excluding exempt material) 10. Stability and Reactivity Reactivity: No specific reactivity test data is available for this mixture. Under normal conditions of storage and use, hazardous reactions are not expected. Incompatible materials: Oxidizers, anionic detergents. Chemical stability: This product is stable at ambient temperatures and pressures. Conditions to avoid: Temperatures above 50°C or below 10°C. Hazardous decomposition products: None known. 11. Toxicological Information Acute Toxicity: Toxicity data is not available for this mixture. Data below are estimates based on summation methods. Test Results Classification (A.0.4.1(c)) Basis (A.1.3.6.1) Oral > 2000mg/kg Not applicable Ingredient literature (Additive formula) Dermal > 2000mg/kg Not applicable Ingredient literature (Additive formula) Inhalation > 20 mg/L Not applicable Ingredient literature (Additive formula) Eye Damage/Irritation Irritation Category 2A Ingredient literature Skin Damage/Irritation Not applicable Not applicable Ingredient literature Summary: Skin and eye contact are most likely routes of exposure. Exposure causes minor skin irritation and serious eye irritation. Subchronic/Chronic Toxicity: Test Results Classification Basis Skin Sensitization Not a sensitizer Not applicable Ingredient literature. Summary: Repeated or prolonged contact causes skin or eye irritation. Carcinogens - Ingredients are not listed on the NTP Report on Carcinogens, IARC Monographs or by OSHA Other data - No other toxicological information is available for this mixture. QUAT TUBERCULOCIDAL HUSKY 814 Q/T TUBERCULOCIDAL SPRAY DISINFECTANT Version: 002 Date issued: 31. 12. 2014 Revision Date: 14. 04. 2016 Page 3 of 3 12. Ecological Information This material has not been tested for acute environmental effects. Persistence and degradability: Material is not persistent. All organic components > 1% are readily biodegradable. Bio-accumulative potential: No evidence to suggest bio-accumulation will occur. Mobility: Accidental spillage may lead to penetration of soil and groundwater. 13. Disposal Considerations Do not contaminate water, food or feed by disposal. Pesticide wastes are acutely hazardous. Improper d isposal of excess pesticide, spray, or mixture of rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label directions, contact your State Pesticide or Environmental Control Agency, or the hazardous waste repres entative at the nearest EPA Regional Office for guidance. Container Disposal: Non-refillable container. Do not reuse or refill this container. Offer for recycling if available. Triple rinse container promptly after emptying. Then offer for recycling or rec onditioning, or puncture and dispose of in a sanitary landfill, or incinerate, or if allowed by state and local authorities, burn. If burned, stay out of smoke. If container is one gallon or less, wrap empty container in plastic bag and discard in trash. 14. Transport Information Proper Shipping Name: Not regulated RQ - Not Applicable Shipping emergency phone: 800-424-9300 Transport hazard class: Not Applicable Hazard Label: Not Applicable Packing Group: Not Applicable Emergency Guide No.: Not Applicable Marine Pollutant: No 15. Regulatory Information Inventory status: All components are listed on TSCA(US), EINECS/ELINCS(EU), DSL(Canada), AICS(Australia), ENCS(Japan). FIFRA: This product is a U.S. EPA Registered pesticide, EPA Reg. No. 1839-83-8155, and is subject to certain labeling requirements under Federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide products. The hazard information required on the pesticide label is reproduced here. CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using toba cco. The pesticide label also includes other important information, including directions for use. OSHA Hazard Communication Standard: This product meets the §1910.1200 definition of a "Hazardous Chemical". Superfund Amendments and Reauthorization Act of 1986 Title III (EPCRA) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard No Fire Hazard No Reactive Hazard No Sudden Release of Pressure Hazard No Superfund Amendments and Reauthorization Act of 1986 Title I II (EPCRA) Section 313 *Chemicals marked with an asterisk in “3. Composition/Information on Ingredients” are subject to reporting requirements for Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40CFR Part 372. Pennsylvania/New Jersey/Massachusetts Right to Know See “3. Composition/Information on Ingredients” for hazardous and top five ingredients over 1% (w/w). California Proposition 65: This product does not contain a listed substance known to the State of California to cause cancer, birth defects or other reproductive harm, at levels which would require a warning under the statute. 16. Other information Date issued: 31. 12. 2014 F814-001 Revision: 14. 04. 2016 Version: 002 Revised pH Disclaimer: No representation or warranty, either expressed or implied, of merchantability, fitness for a particular purpose, or of any other nature, is made with respect to information concerning the product referred to in this document. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, it is impossible to foresee every health effect or exposure risk incur red by the use of this product. All chemicals present some degree of hazard and should be used with caution. The information and recommendations contained herein are presented in good faith. The user should review this information in conjunction with their knowledge of the application intended to determine the suitability of this product for such purpose. In no event will the supplier be responsible for any damages of any nature whatsoever, resulting from the use, reliance upon, or the misuse of thi s information. Furthermore, it is the direct responsibilit y of the user to comply with all applicable regulations governing the use and disposal of this material. Prepared by: R&D, Canberra Corporation